Just after the post is saved
function add_image_to_acf_field($post_id) {
if (has_post_thumbnail($post_id)) {
$post_thumbnail_id = get_post_thumbnail_id($post_id);
// notice that I'm using the field key here
update_field('field_4fc5ab37e1819lol', $post_thumbnail_id, $post_id');
}
}
add_action('save_post', 'add_image_to_acf_field');