I’m not sure I completely understand, but would something like this work?
function append_url_to_field($new_input) {
$current_values = get_field('list_of_urls', 'option')?:'';
if($current_values) {
$current_values .= ',';
}
$current_values .= $new_input;
}
You create a simple ‘text’ field on an options page/or other, and simply append it the new value to the existing value.
Whenever you want to work with the domains you can use explode(',', $field_value)
to get an array of urls.